Single electron transfer-induced Grignard cross-coupling involving ion radicals as exclusive intermediates.
نویسندگان
چکیده
The mechanism of the previously developed cross-coupling reaction of aryl Grignard reagents with aryl halides was explored in more detail. Single electron transfer from an aryl Grignard reagent to an aryl halide initiates a radical chain by giving an anion radical of the aryl halide. The following propagation cycle consists entirely of anion radical intermediates.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 4 شماره
صفحات -
تاریخ انتشار 2013